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Ions derived from dianthrylethane species. How the mode of linking affects the intramolecular electron transfer

…, A Bohnen, M Ehrenfreund, W Wohlfarth…

文献索引:Becker, Bardo; Bohnen, Angelika; Ehrenfreund, Marianne; Wohlfarth, Werner; Sakata, Yoshiteru; Huber, Walter; Muellen, Klaus Journal of the American Chemical Society, 1991 , vol. 113, # 4 p. 1121 - 1127

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被引用次数: 14

摘要

Abstract: Chemical and electrochemical reduction of dianthryl compounds affords mono-, di-, tri-, and tetraanions via successive electron-transfer processes. The diamagnetic or paramagnetic ions are characterized by NMR and ESR spectroscopy, respectively, by cyclic voltammetry, and by quenching reactions. The title dianthryl systems have in common that two anthracene units are linked by ethane bridges in a sterically variable fashion. It ...