Tetrahedron

EPR-studies on the chelation of alkali metal cations by radical-anions—IV Radical-anions derived from 1, 2, 4, 5-tetramesitoybenzene

BJ Herold, M Celina, RLR Lazana, HM Novais

文献索引：Herold,B.J. et al. Tetrahedron, 1977 , vol. 33, p. 517 - 521

全文：HTML全文

被引用次数: 6

摘要

1, 2, 4, 5-Tetramesitoylbenzene was synthesized and reduced with alkali metals as well as electrolytically. EPR spectra of the resulting radical-ion pairs are reported and discussed. The electron-spin densities obtained from temperature coefficient and marked solvent dependency. These effects are compared with the ones observed in the corresponding radical-ion pairs of o-dimesitoylbenzene for which some new data are also reported.