Intramolecular. alpha.-amidoyl-to-aryl 1, 5-hydrogen atom transfer reactions. Heteroannulation and. alpha.-nitrogen functionalization by radical translocation

V Snieckus, JC Cuevas, CP Sloan, H Liu…

文献索引：Snieckus; Cuevas; Sloan; Liu; Curran Journal of the American Chemical Society, 1990 , vol. 112, # 2 p. 896 - 898

全文：HTML全文

被引用次数: 134

摘要

When the generation of oxygen-centered radicals at remote sites is followed by intramolecular hydrogen atom transfer, a powerful method to functionalize organic molecules results2 This strategy has recently been extended to the tin hydride method by generating carbon-centered radicals at remote sites (such as protecting groups) and translocating these radicals by 1, 5-hydrogen atom transfer prior to~ yclization.~ In ...