Monomeric Organogallium-Nitrogen Compounds. Chemistry of Et2GaNH [C6H2 (2, 4, 6-t-Bu) 3] with Decomposition to the Metallacycle {EtGaNH [C6H2 (4, 6-t …

OT Beachley, DB Rosenblum, MR Churchill…

文献索引：Beachley Jr.; Rosenblum, Daniel B.; Churchill, Melvyn Rowen; Churchill, David George; Krajkowski, Lynn M. Organometallics, 1999 , vol. 18, # 13 p. 2543 - 2549

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被引用次数: 9

摘要

Two monomeric gallium-nitrogen compounds Et2GaNH [C6H2 (2, 4, 6-t-Bu) 3] and EtGa {NH [C6H2 (2, 4, 6-t-Bu) 3]} 2 have been prepared and characterized. The compound Et2GaNH [C6H2 (2, 4, 6-t-Bu) 3], but not EtGa {NH [C6H2 (2, 4, 6-t-Bu) 3]} 2, decomposes at room temperature to form a new metallacyclic derivative {EtGaNH [C6H2 (4, 6-t-Bu) 2 (CMe2CH2-2)]} 2, GaEt3, and H2N [C6H2 (2, 4, 6-t-Bu) 3].