Condensations by Sodium. VIII. Solvent Exchange Reactions, Preparation of Phenylmalonic Acid, and Comments on Some Mechanisms of Reactions which Employ …
AA Morton, I Hechenbleikner
文献索引：Morton; Hechenbleikner Journal of the American Chemical Society, 1936 , vol. 58, p. 1024,2599,2604
When benzene or a mixture of benzene and ligroin was used as the solvent for the preparation of amylsodium from amyl chloride and sodium by the recently described'synthesis of organo-metallic compounds, the product after carbonation was benzoic instead of caproic acid. Exchange of phenyl for the amyl radical was complete and the yield of benzoic acid, calculated on the basis of a molecule of acid for every one of ...
