H-Phosphonylphosphonate triethylester: the first member of a novel family of stable bisphosphorylated compounds; its short synthesis and reactivity with aldehydes
P Bisseret, J Eustache
文献索引:Bisseret, Philippe; Eustache, Jacques Tetrahedron Letters, 2001 , vol. 42, # 48 p. 8451 - 8453
A short preparation of the first member (1) of the novel H-phosphonylphosphonate family is described. Its reaction with aldehydes provides a straightforward access to the hitherto almost unprecedented class of α-hydroxyphosphinylphosphonates 3 of potential value in particular in medicinal chemistry.