Asymmetric routes to pentadec-1-en-4-ol: application to the syntheses of aculeatins F and epi-F,(R)-and (S)-5-hexadecanolide and a formal synthesis of solenopsin
A Harbindu, BM Sharma, P Kumar
文献索引：Harbindu, Anand; Sharma, Brijesh M.; Kumar, Pradeep Tetrahedron Asymmetry, 2013 , vol. 24, # 5-6 p. 305 - 314
A short and simple route to the synthesis of pentadec-1-en-4-ol, an important synthetic building block for the aculeatins F and epi-F, insect pheromone 5-hexadecanolide, solenopsin and various other natural products has been developed via proline-catalyzed α- aminoxylation of an aldehyde and hydrolytic kinetic resolution of a terminal epoxide. While the synthesis of aculeatins F and epi-F has been accomplished using a PIFA promoted ...
