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Synthesis of Nitric Esters by the Addition of Nitric Acid to the Ethylene Oxide Ring1

PL Nichols Jr, AB Magnusson…

文献索引:Nichols et al. Journal of the American Chemical Society, 1953 , vol. 75, p. 4255,4257

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被引用次数: 42

摘要

A study of factors influencing the yield of products resulting from the addition of nitric acid to ethylene oxide (oxirane) compounds has been made. For reactions in aqueous solutions, it was demonstrated that the ratio of nitrated products to side products was directly proportional to the ratio of nitrate ion (in moles per liter) to water (in moles per liter) at a given temperature. Several new nitrato alcohols have been prepared in good yield by two ...