Organometallics

Ruthenium-Amine Electronic Coupling Bridged through Phen-1, 3-diyl Versus Phen-1, 4-diyl: Reverse of the Charge Transfer Direction

JH Tang, SH Wu, JY Shao, HJ Nie, YW Zhong

文献索引：Tang, Jian-Hong; Wu, Si-Hai; Shao, Jiang-Yang; Nie, Hai-Jing; Zhong, Yu-Wu Organometallics, 2013 , vol. 32, # 16 p. 4564 - 4570

全文：HTML全文

被引用次数: 10

摘要

Three tris-bidentate cyclometalated ruthenium complexes with a di (p-anisyl) amino [5 (PF6)], di (p-tolyl) amino [6 (PF6)], or di (p-chlorophenyl) amino [7 (PF6)] substituent on the cyclometalating phenyl ring have been prepared, where the amine nitrogen is in the meta position to the cyclometalated site (bridged through the phen-1, 3-diyl unit). The structure of 6 (PF6) has been confirmed by single-crystal X-ray diffraction analysis. Two consecutive ...