Journal of the American Chemical Society

General transannulation approach to angular triquinanes. Total syntheses of (.+-.)-pentalenene and (.+-.)-epi-pentalenene

G Mehta, KS Rao

文献索引：Mehta, Goverdhan; Rao, Kasibhatla Srinivas Journal of the American Chemical Society, 1986 , vol. 108, # 25 p. 8015 - 8021

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被引用次数: 44

摘要

Abstract: A short, general approach for the synthesis of angular triquinanes is delineated. The key element of this approach is the carbonium-ion-mediated transannulation in the bicyclo [6.3. 0] undecane system. New syntheses of appropriately functionalized bicyclo [6.3. 0] undecanes 1 la and 1 lb from cheap, abundantly available 1, 5-~ yclooctadiene have been developed. These have been cyclized in formic acid and elaborated to tricycl0 [6.3. ...