Polymer

Synthesis and characterization of side chain polymer with helical PLLA segments containing mesogenic end group

H Chen, Q Xue, Z Li, L Sun, Q Zhang

文献索引：Chen, Hongru; Xue, Qingbin; Li, Zhuohua; Sun, Lingmin; Zhang, Quanxuan Polymer, 2011 , vol. 52, # 2 p. 400 - 408

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被引用次数: 8

摘要

Series of mesogenic biphenol derivatives HO6OPPOn (n= 4, 6, 8) were prepared by asymmetric reaction and purified. Then HOLAxO6OPPOn were prepared with controlled molecular weights by adjusting the feed ratios of HO6OPPOn, SnOct2 catalyst and LLA by Ring-Opening Polymerization. P-AOLAxO6OPPOn materials were obtained in high yields by the free radical polymerization of polymerizable macromonomers of AOLAxO6OPPOn ...