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A new approach to the construction of diamondoid hydrocarbons. Synthesis of anti-tetramantane

W Burns, MA McKervey, TRB Mitchell…

文献索引:Burns,W. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 906 - 911

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被引用次数: 49

摘要

Abstract: A new approach to the construction of diamondoid hydrocarbons is described. The method is general and could, in principle, be used as either a single or a double homologation of any lower member of the diamondiod series into a higher member. It is illustrated by the conversion of diamantane into triamantane (single homologation) and by the first synthesis of antitetramantane (double homologation), one of three topological ...