The electronic structure and second-order nonlinear optical properties of donor-acceptor acetylenes: A detailed investigation of structure-property relationships

AE Stiegman, E Graham, KJ Perry…

文献索引：Stiegman; Graham, Eva; Perry, Kelly J.; Khundkar, Lutfur R.; Cheng; Perry, Joseph W. Journal of the American Chemical Society, 1991 , vol. 113, # 20 p. 7658 - 7666

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被引用次数: 170

摘要

Abstract: A series of donoracceptor acetylene compounds was synthesized in which systematic changes in both the conjugation length and the donoracceptor strength were made. The effect of these structural changes on the spectroscopic and electronic properties of the molecules and, ultimately, on the measured second-order molecular hyperpolarizabilities (@) was investigated. It was found that increases in the ...