Synthesis and alkyne-coupling chemistry of cyclomanganated 1-and 3-acetylindoles, 3-formylindole and analogues
GJ Depree, L Main, BK Nicholson, NP Robinson…
文献索引：Depree, Gary J.; Main, Lyndsay; Nicholson, Brian K.; Robinson, Nicholas P.; Jameson, Geoffrey B. Journal of Organometallic Chemistry, 2006 , vol. 691, # 4 p. 667 - 679
The syntheses are reported of new cyclomanganated indole derivatives (1-acetyl-κO-indolyl- κC2) dicarbonylbis (trimethylphosphite) manganese (2),(1-methyl-3-acetyl-κO-indolyl-κC2) tetracarbonylmanganese (4),(3-formyl-κO-indolyl-κC2) tetracarbonylmanganese (5a) and (1- methyl-3-formyl-κO-indolyl-κC2) tetracarbonylmanganese (5b). The unusually complicated crystal structure of 5b has been determined, the first for a cyclomanganated aryl aldehyde. ...
