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Thermally irreversible photochromic systems. Reversible photocyclization of 1, 2-diselenenylethene and 1, 2-diindolylethene derivatives

Y Nakayama, K Hayashi, M Irie

文献索引:Nakayama, Yasuhide; Hayashi, Koichiro; Irie, Masahiro Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2592 - 2596

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被引用次数: 120

摘要

Diarylethene derivatives with selenophene or indole rings were synthesized in an attempt to obtain thermally stable photochromic compounds having the absorption bands at longer wavelengths and to confirm our previous theoretical prediction for molecular design of thermally irreversible photochromic compounds. The absorption maxima of the closed-ring forms of 2, 3-bis (2, 4, 5-trimethyl-3-selenenyl) maleic anhydride (6) and 2, 3-bis (1, 2- ...