Substituent effects in cationic bis (arene) chromium compounds. Electronic and ESR spectra, and an x-ray structure of bis (1, 3, 5-triisopropylbenzene) chromium (I) …
…, DL Ward, B McCulloch, CH Brubaker Jr
文献索引:Li, Tomi Ting-Tung; Kung, Wei-jen; Ward, Donald L.; McCulloch, Beth; Brubaker, Carl H. Organometallics, 1982 , vol. 1, p. 1229 - 1235
For a series of monosubstituted bis (arene) chromium cations, the UV ligand-metal charge- transfer (LMCT) bands and electron spin resonance (ESR) parameters do not depend on the nature or ring substituents. However, as the number of electron-donating groups on the arene ring are increwd inductive effects become more significant. X-ray crystallography has been applied to determine the molecular structure of bis-(1, 3, 5-triisopropylbenzene) ...