Aryl− Oxazoline Chelates of First-Row Transition Metals: Structures of {κ-C, N-(o-C6H4) CMe2 (COCH2CMe2N)} FeCl (py) and [(κ-C, N-(o-C6H4) CMe2 ( …

…, ER Bartholomew, PT Wolczanski, EB Lobkovsky

文献索引：Volpe, Emily C.; Manke, David R.; Bartholomew, Erika R.; Wolczanski, Peter T.; Lobkovsky, Emil B. Organometallics, 2010 , vol. 29, # 24 p. 6642 - 6652

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被引用次数: 5

摘要

Synthetic efforts to attach aryl-oxazoline chelates to first-row transition metals featured heterolytic CH bond activation, oxidative addition, and aryl anion equivalents, but only the latter two methods were productive, yielding [{κ-C, N-(o-C6H4) CMe2 (COCH2CMe2N)} Cr] 2 (μ-Cl) 2 (6 2),{κ-C, N-{(o-C6H4) CMe2 (COCH2CMe2N)} Fe (py) Cl (7), and {κ-C, N-(o- C6H4) CMe2 (COCH2CMe2N)} 2Ni (9), for example.