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Tetrahedron Letters

(3, 3-Diisopropoxypropyl) triphenylarsonium ylide: A new synthetic equivalent of β-formyl vinyl anion

P Chabert, JB Ousset, C Mioskowski

文献索引:Chabert, P.; Ousset, J. B.; Mioskowski, C. Tetrahedron Letters, 1989 , vol. 30, # 2 p. 179 - 182

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被引用次数: 21

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The synthesis and the reactivity of (3,3-diisopropoxypropyl) triphenylarsonium ylide are described. This new reagent can be considered as a β-formyl vinyl anion equivalent, as shown by the conversion of aldehydes to 4-hydroxy-2-(E)-enals in very mild conditions.