Angewandte Chemie International Edition

RuO2 clusters within LTA zeolite cages: consequences of encapsulation on catalytic reactivity and selectivity

BZ Zhan, E Iglesia

文献索引：Zhan, Bi-Zeng; Iglesia, Enrique Angewandte Chemie - International Edition, 2007 , vol. 46, # 20 p. 3697 - 3700

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被引用次数: 31

摘要

The consequences of cluster size and spatial constraints are critical for the design of selective catalysts. Zeolites and other microporous solids provide essential scaffolds for controlling the size and accessibility of active structures and the nature of spatial constraints around such sites.[1, 2] The size-dependent redox properties of oxide nanoclusters lead to diverse catalytic properties for a given composition,[3–5] but the synthesis and stability of ...