Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of furanyl (γ)-and pyranyl (δ)-lactols

MF Buffet, DJ Dixon, SV Ley, DJ Reynolds…

文献索引：Buffet, Marianne F.; Dixon, Darren J.; Ley, Steven V.; Reynolds, Dominic J.; Storer, R. Ian Organic and Biomolecular Chemistry, 2004 , vol. 2, # 8 p. 1145 - 1154

全文：HTML全文

被引用次数: 22

摘要

Tetrahydropyran and tetrahydrofuran containing natural products, drugs and agrochemicals often possess carbon–carbon bonds adjacent to the heteroatom. Consequently, new methods for the construction of anomeric carbon–carbon bonds are of considerable importance. We have devised a new strategy to access these systems that requires the treatment of O-glycoside alkynyl tributylstannane derivatives of furanyl and pyranyl lactols ...