The Journal of Organic Chemistry

Konig's Adducts of N-Alkyl (aryl) aminoethanols and Quinones. 3, 4-Dihydro-4-alkyl (aryl)-8a-hydroxy-2H-1, 4-benzoxazin-6 (8aH)-ones

K McMurtrey, G Daves, Jr

文献索引：McMurtrey,K.D.; Daves,G.D. Journal of Organic Chemistry, 1970 , vol. 35, # 12 p. 4252 - 4253

全文：HTML全文

被引用次数: 12

摘要

I na cryogenic study of the thermodynamics of hydrogen bond formation in the previously described adduct1 of triethylamine (TEA) and methylene chloride (PIC), we encountered an unexpected reaction at room temperature that yielded chloromethyltriethylammonium chloride (1). This salt crystallized in analytically pure form from a solution of the components containing excess amine. The nmr spectrum [6 (CDC13) 1.50 (t, 9, J= 8 Ha), 3.72 (q, 6, J= ...