Synthesis of Ruthenium Hydride Complexes Containing beta??Aminophosphine Ligands Derived from Amino Acids and their use in the H2??Hydrogenation of Ketones …

K Abdur??Rashid, R Guo, AJ Lough…

文献索引：Abdur-Rashid, Kamaluddin; Guo, Rongwei; Lough, Alan J.; Morris, Robert H.; Song, Datong Advanced Synthesis and Catalysis, 2005 , vol. 347, # 4 p. 571 - 579

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被引用次数: 81

摘要

Abstract The new complexes RuHCl (PPh 2 CH 2 CHRNH 2) 2 and RuHCl (PPh 2 CH 2 CHRNH 2)(R-binap), R= H (Pgly), R= Me [(R)-Pala] were prepared by the substitution of the PPh 3 ligands in RuHCl (PPh 3) 3 or RuHCl (PPh 3)[(R)-binap] with beta-aminophosphines derived from amino acids. The complex trans-RuHCl (Pgly)[(R)-binap] has been characterized by X-ray crystallography. The complex trans-RuHCl [(S)-Ppro] 2 where (S)- ...