Accelerated C–N bond formation in dropcast thin films on ambient surfaces
AK Badu-Tawiah, DI Campbell, RG Cooks
文献索引：Badu-Tawiah, Abraham K.; Campbell, Dahlia I.; Cooks, R. Graham Journal of the American Society for Mass Spectrometry, 2012 , vol. 23, # 9 p. 1461 - 1468,8
Abstract The aza-Michael addition and the Mannich condensation occur in thin films deposited on ambient surfaces. The reagents for both C–N bond formation reactions were transferred onto the surface by drop-casting using a micropipette. The surface reactions were found to be much more efficient than the corresponding bulk solution-phase reactions performed on the same scale in the same acetonitrile solvent. The increase in rate of ...
