Camphene. IV. Interconversions of three homocamphenes

WR Vaughan, DM Teegarden

文献索引：Vaughan,W.R.; Teegarden,D.M. Journal of the American Chemical Society, 1974 , vol. 96, # 15 p. 4902 - 4909

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被引用次数: 8

摘要

Abstract: The preparations of 8-, 9-and 10-homocamphene are described. and their interconversions in acetonitrile-pyruvic acid have been studied and compared with camphene racemization mechanisms. The kinetics of the various processes, which are interrupted before secondary rearrangements become a problem, indicate that each isomer is transformed into its products oia simultaneous (competitive) reactions. hen the present ...