Homogeneous catalysts for selective molecular oxygen driven oxidative decarboxylations

DP Riley, DL Fields, W Rivers

文献索引：Riley, Dennis P.; Fields, Donald L.; Rivers, Willie Journal of the American Chemical Society, 1991 , vol. 113, # 9 p. 3371 - 3378

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被引用次数: 31

摘要

Abstract Cobalt (11) ion has been found to catalyze the molecular oxygen driven oxidation of N-(phosphonomethy1) iminodiacetic acid (PMIDA) to N-(phosphonomethy1) glycine (PMG) in aqueous so1ution. l This homogeneous catalytic conversion is novel and represents, in effect, an oxidative dealkylation of one carboxymethyl moiety yielding the N-substituted glycine. The reaction is selective to the desired product PMG when carried out at the ...