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The Journal of organic chemistry

Preparation of 2, 8-Dihydroxy-5, 6, 11, 12-Tetrahydro-5, 11-epoxydibenzo [a, e] cycloctene, an Analogue of Kagan's Ether

M Harmata, M Kahraman

文献索引:Harmata, Michael; Kahraman, Mehmet Journal of Organic Chemistry, 1999 , vol. 64, # 13 p. 4949 - 4952

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被引用次数: 14

摘要

As part of our work with Kagan's ether 1 we came to need an analogue of 1 which could be used to prepare a variety of ligands for the purpose of constructing chiral catalysts and/or large molecular architectures, such as molecular squares or other large ring systems. 1-3 We decided to pursue the synthesis of the simple dihydroxy compound 2. This report describes the synthesis of racemic and both enantiomerically enriched (R, R) and