Crystalline films of interdigitated structures formed via amidinium-carboxylate interactions at the air-water interface

…, J Als-Nielsen, R Granek, G v. Kiedrowski…

文献索引：Kuzmenko; Kindermann; Kjaer; Howes; Als-Nielsen; Granek; Kiedrowski; Leiserowitz; Lahav Journal of the American Chemical Society, 2001 , vol. 123, # 16 p. 3771 - 3783

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被引用次数: 25

摘要

Electrostatic interactions between amidinium and carboxylates were used for the construction of interdigitated architectures at the air-solution interface. Spreading the water- insoluble amphiphile p-pentadecylbenzoic acid (A) on an aqueous solution of p- methylbenzamidinium (B) ions results in an intercalation of the water-soluble base between the acidic headgroups of the water-insoluble amphiphile to form an amorphous ABAB ...