A self-folding metallocavitand

…, J Chen, DM Rudkevich, J Rebek

文献索引：Luecking; Chen; Rudkevich; Rebek Jr. Journal of the American Chemical Society, 2001 , vol. 123, # 41 p. 9929 - 9934

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被引用次数: 28

摘要

The synthesis and characterization of novel metallocavitand 6 are described. This is a covalent hybrid of a deepened, self-folding cavity and a Zn-phenanthroline fragment. Host 6 features a large molecular cavity of~ 8× 10 Å dimensions, and the metal binding site is directed in toward the cavity. Binding abilities of the metallocavitand in solution was demonstrated for quinuclidine 11 and Dabco 12 using UV-vis and 1H NMR spectroscopy. ...