Novel triazenes and triazolines from the base-catalyzed hydrolysis of 1, 3-dialkyl-3-acyltriazenes

RH Smith Jr, BD Wladkowski, JA Herling…

文献索引：Smith, Richard H.; Wladkowski, Brian D.; Herling, Julie A.; Pfaltzgraff, Timothy D.; Taylor, Jesse E.; et al. Journal of Organic Chemistry, 1992 , vol. 57, # 24 p. 6448 - 6454

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被引用次数: 11

摘要

Several years ago we described the synthesis of a new class of alkyltriazenes, 1, 3-dialky1-3- acyltriazenes.'These compounds are more stable than the parent l, &dialkyltriazenes, which undergo rapid specific acid-catalyzed decomposition in aqueous buffers to produce alkylamines and an alkyldiazonium ion intermediate. 2 In our initial report,'we noted that the hydrolytic decomposition of 1, 3-dialkyl-3-acyltriazenes exhibits a complex dependence ...