Functionalized carbosilane dendritic species as soluble supports in organic synthesis

NJ Hovestad, A Ford, JTBH Jastrzebski…

文献索引：Hovestad, Neldes J.; Ford, Allan; Jastrzebski, Johann T. B. H.; Van Koten, Gerard Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6338 - 6344

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被引用次数: 49

摘要

A new methodology, which is compatible with the use of reactive organometallic reagents, has been developed for the use of carbosilane dendrimers as soluble supports in organic synthesis. Hydroxy-functionalized dendritic carbosilanes Si [CH2CH2CH2SiMe2 (C6H4CH (R) OH)] 4 (G0-OH, R= H or (S)-Me) and Si [CH2CH2CH2Si [CH2CH2CH2SiMe2 (C6H4CH (R) OH)] 3] 4 (G1-OH, R= H or (S)-Me) were prepared and subsequently converted into the ...