Rhodium pincer complexes of 2, 2′-bis (diphenylphosphino) diphenylamine
AM Winter, K Eichele, HG Mack, S Potuznik…
文献索引：Winter, Angelika M.; Eichele, Klaus; Mack, Hans-Georg; Potuznik, Suzan; Mayer, Hermann A.; Kaska, William C. Journal of Organometallic Chemistry, 2003 , vol. 682, # 1-2 p. 149 - 154
The novel pincer ligand 2, 2′-bis (diphenylphosphino) diphenylamine (1) has been synthesized by treatment of 2, 2′-dibromodiphenylamine with n-butyl lithium and subsequent reaction with diphenylchlorophosphine. When ligand 1 is treated with RhCl3 hydrate the dinuclear complex 1a forms which can be converted into the square planar carbonyl complex 1c upon reduction with Na/Hg in the presence of CO. Depending on the ...
