The syntheses of the triazinyl-based bis-aryl phosphates 2 and 3, and of the aminopyrimidyl- based aryl phosphate 4 are described. Each compound contains a diaryl ether-phosphate structural motif. The synthetic route to bis-aryl phosphates 2 and 3 consisted in two nucleophilic substitution reactions with amines from cyanuric chloride, followed by a Suzuki coupling with the resulting 2, 4-diamino-6-chloro-1, 3, 5-triazine derivative 12 to introduce ...
