Synthesis, Structural Characterization, and Catalytic Activity of IPrNi (styrene) 2 in the Amination of Aryl Tosylates

MJ Iglesias, JF Blandez, MR Fructos, A Prieto…

文献索引：Iglesias, Maria Jose; Blandez, Juan F.; Fructos, Manuel R.; Prieto, Auxiliadora; Alvarez, Eleuterio; Belderrain, Tomas R.; Nicasio, M. Carmen Organometallics, 2012 , vol. 31, # 17 p. 6312 - 6316

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被引用次数: 26

摘要

A novel bis-styrene IPrNi0 derivative has been synthesized from the reaction of Ni (COD) 2 and free 1, 3-bis (2, 6-diisopropylphenyl) imidazolidene (IPr) ligand in the presence of styrene. The complex has been characterized by spectroscopic data as well as by X-ray crystallography. Its catalytic performance in the amination reaction of aryl tosylates is also reported. The catalytic reactions proceed in a very selective manner, affording moderate to ...