Tetrahedron

Pericyclic reactions of cyclopentadienones with nonactivated olefins in phenolic solvents. Enhancement of the reactivity and periselectivity

T Jikyo, M Eto, K Harano

文献索引：Jikyo, Tamaki; Eto, Masashi; Harano, Kazunobu Tetrahedron, 1999 , vol. 55, # 19 p. 6051 - 6066

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被引用次数: 16

摘要

The solvent effect of phenols on the reactivity and periselectivity for the pericyclic reactions of cyclopentadienones with olefins involving conjugated medium-ring polyenes has been investigated. The use of phenols as a solvent accelerates the reaction rates of cycloadditions of cyclopentadienones with nonactivated olefins. In the reaction of cycloheptatriene in p-chlorophenol, the exo [4+ 6] π cycloadduct was produced ...