Do carbanions undergo 1, 2 hydrogen transfers in the gas phase?

…, GW Adams, JC Sheldon, JH Bowie

文献索引：Dua, Suresh; Adams, Gregory W.; Sheldon, John C.; Bowie, John H. Journal of the Chemical Society. Perkin Transactions 2, 1996 , vol. 6, p. 1251 - 1256

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被引用次数: 4

摘要

Certain anions X–CH–CH–Y and X–CHCH–Y interconvert under collisional activation conditions in the gas phase. Experiments designed to probe the mechanism (s) of particular interconversions suggest (i) that the ions MeO–CH–CH–CN and MeO–CH–CH–CN interconvert 1, 2 H transfer processes, and (ii) when X= Ph and Y= COMe