Tetrahedron

Photoinduced hydrogen atom abstraction in N-(adamantyl) phthalimides: structure–reactivity study in the solid state

…, M Horvat, O Franković, K Mlinarić-Majerski, J Neudörfl…

文献索引：Basaric, Nikola; Horvat, Margareta; Frankovic, Oliver; Mlinaric-Majerski, Kata; Neudoerfl, Joerg; Griesbeck, Axel G. Tetrahedron, 2009 , vol. 65, # 7 p. 1438 - 1443

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被引用次数: 18

摘要

Adamantyl-functionalized phthalimides were synthesized and the probability of intramolecular photochemical hydrogen atom abstraction in the solid state analyzed by X- ray crystallographic analyses. These analyses and solid-state photolyses showed that the parameters determining photochemical reactivity for typical carbonyl compounds in the solid state can also be extended to phthalimides. Only N-(2-adamantyl) phthalimide underwent ...