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Preparation of α-Carbalkoxyalkyl Methacrylates by Pyrolysis of the Corresponding α-Acetoxyisobutyrates

EM Filachione, ML Fein, JH Lengel…

文献索引:Filachione et al. Journal of the American Chemical Society, 1948 , vol. 70, p. 527

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被引用次数: 5

摘要

Summary It has been found that D-glucose and L-arabinose in 50.5% sulfuric acid solutions show strong absorption at wave length 2840 A. which is characteristic for carbonyl- containing compounds. After neutralization with sodium bicarbonate the slightly acidic solution still exhibits this band which, however, instantaneously disappears on rendering the solution barely alkaline. A possible mechanism is suggested for explanation of the ...