Rh (I)-Catalyzed Olefin Hydroarylation with Electron-Deficient Perfluoroarenes

…, J Zhang, RS Manan, P Zhao

文献索引：Wei, Ye; Zhao, Huaiqing; Kan, Jian; Su, Weiping; Hong, Maochun Journal of the American Chemical Society, 2010 , vol. 132, p. 2522 - 2523

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被引用次数: 61

摘要

Assisted by a partially aqueous media, a catalyst system of [Rh (cod)(OH)] 2 and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C− H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.