Highly Efficient Synthesis of Stereodefined Multisubstituted 1, 4??Dicyano??and 1??Cyano??1, 3??butadienes and Their Reactions with Organolithium Reagents
C Wang, C Wang, Q Wang, Z Wang…
文献索引:Wang, Congyang; Wang, Chao; Wang, Qifeng; Wang, Zhihui; Sun, Hui; Guo, Xiangyu; Xi, Zhenfeng Chemistry - A European Journal, 2007 , vol. 13, # 22 p. 6484 - 6494
Abstract Stereodefined multisubstituted 1-cyano-and 1, 4-dicyano-1, 3-butadiene derivatives were obtained in excellent yields of the isolated product from their corresponding monohalo- and dihalobutadienes and CuCN. This reaction proceeded with high stereoselectivity and retention of the stereochemistry of the starting halobutadienes. A study of the utility of the thus-obtained 1-cyano-and 1, 4-dicyano-1, 3-butadiene derivatives was demonstrated by ...