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The Journal of Organic Chemistry

Amidation and Hydrazidation of O-Aryl Phosphorodichloridothioates1

EH Blair, H Tolkmith

文献索引:Blair,E.H.; Tolkmith,H. Journal of Organic Chemistry, 1960 , vol. 25, p. 1620 - 1627

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被引用次数: 11

摘要

0-Aryl phosphorodichloridothioates on reaction with ammonia and aliphatic amines gave 0- aryl phosphoramidochloridothioates and 0-aryl phosphorodiamidothioates in high yields. 0- Aryl phosphorodichloridothioates also react with substituted hydrazines to give 0-aryl phosphorohydrazidochloridothioates and 0-aryl phosphorodihydrazidothioates in high yields. The reactions were found to be dependent on temperature of reaction, mole ratio, ...