Stereospecific Aerobic Oxidative Dehydrocoupling of P (O)–H Bonds with Amines Catalyzed by Copper

Y Zhou, J Yang, T Chen, SF Yin, D Han…

文献索引：Zhou, Yongbo; Yang, Jia; Chen, Tieqiao; Yin, Shuang-Feng; Han, Daoqing; Han, Li-Biao Bulletin of the Chemical Society of Japan, 2014 , vol. 87, # 3 p. 400 - 402

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被引用次数: 3

摘要

Copper-catalyzed stereospecific oxidative dehydrocouplings of P (O)–H bonds with amines under air took place efficiently at room temperature to afford the corresponding amidophosphorus compounds in high yields. Mechanistic studies showed that this dehydrocoupling reaction proceeded stereospecifically with inversion of stereochemistry at phosphorus.