Synthesis of bis (trifluoromethyl) phenylthallium and bis (trifluoromethyl) thallium acetate. Oxidative trifluoromethylation with bis (trifluoromethyl) thallium (III) …
HK Nair, JA Morrison
文献索引：Nair, H. K.; Morrison, J. A. Inorganic Chemistry, 1989 , vol. 28, p. 2816 - 2820
The reaction of Cd (CF3) 2. glyme with TlPhC12 forms T1Ph (CF3) 2, which is isolated in 87% yield after 72 h. If TIPh (OAc), is the thallium source, T1Ph (CF3) 2 is generated in 2 h; however, the isolated yield is lower because acetate reacts with Cd (CF3) 2. glyme, resulting in CHICOF. The interaction of Cd (CF3) 2. glyme with TI (OAC)~ produces T1 (CF3) 20Ac, 46%, within 45 min. The possibility of utilizing (trifluoromethyl) thallium (III) species in ...
