Synthesis, structure and magnetic properties of tetrakis-μ-carboxylato-bis (dodecylnicotinato) dicopper (II) complexes; crystal and molecular structure of the decyl …

…, Z Chaia, OE Piro, D Guillon, FD Cukiernik

文献索引：Rusjan, Marcia; Chaia, Zulema; Piro, Oscar E.; Guillon, Daniel; Cukiernik, Fabio D. Acta Crystallographica Section B: Structural Science, 2000 , vol. 56, # 4 p. 666 - 672

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被引用次数: 19

摘要

Dodecylnicotinate bis-adducts of binuclear copper carboxylates, of the general formula Cu2 (O2CCn− 1H2n− 1) 4 (C5H4NCOOC12H25) 2, were synthesized for n= 10, 12, 14, 16, 18 and 20, and their crystal structure, thermal behavior and magnetic properties studied. The molecular structure of the decyl derivative has been determined from single-crystal X-ray diffraction data. The dimer is centrosymmetric with the CuII ions in a square-pyramidal ...