A new geometrical form for germanium. Synthesis and structure of tetraethylammonium 2-chloro-2, 2'-spirobis (1, 3, 2-benzodioxa) germole (IV)

AC Sau, RO Day, RR Holmes

文献索引：Sau, Arjun C.; Day, Roberta O.; Holmes, Robert R. Journal of the American Chemical Society, 1980 , vol. 102, p. 7972 - 7973

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被引用次数: 23

摘要

Although pentacoordinated Ge (1V) species' having a trigonal bipyramidal structure have been characterized by X-ray crystallography, no reports are available concerning the structure of a spirocyclic pentacoordinate Ge (1V) compound. We report herein the preparation and X-ray crystal structure of the first pentacoordinated Ge (1V) compound having a square pyramidal conformation. The compound, tetraethylammonium 2-chloro-2, ...