1, 2-Migrations in free radicals related to coenzyme B12-dependent rearrangements

S Wollowitz, J Halpern

文献索引：Wollowitz, Susan; Halpern, Jack Journal of the American Chemical Society, 1988 , vol. 110, # 10 p. 3112 - 3120

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被引用次数: 58

摘要

Summary Laser flash photolysis at 354.7 nm in the ligand field absorption region of (CO), W= C (OMe) Ph in solution results in prompt formation of a transient with a microsecond lifetime. Evidence for primary photodissociation of CO is presented, in agreement with earlier steady-state photolysis studies? but the transient decay is independent of CO concentration in solution. It is concluded on the basis of both kinetic and resonance ...