Absolute rate constants for the reaction of triethylsilyl radicals with ring-substituted benzyl chlorides

C Chatgilialoglu, KU Ingold…

文献索引：Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. Journal of Organic Chemistry, 1987 , vol. 52, # 5 p. 938 - 940

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被引用次数: 17

摘要

'From ref 18. bAbsolute rate constants measured at 24 f 2" C in EtSiH: Me&OOCMe, solvent by using benzil as probe. Errors correspond to 95% confidence limits but include only random error. cRelative rate constants measured at 40" C in EtsSiH solvent. Calculated at 24" C from the Arrhenius parameters given in the supplementary material of ref 3. tions by the triethylsilyl radical., Our results led us to propose that charge transfer in the transition ...