Toward an understanding of the cubyl and related caged carbocations

…, NJ Head, WK Janowski, CH Schiesser

文献索引：Della; Head; Janowski; Schiesser Journal of Organic Chemistry, 1993 , vol. 58, # 27 p. 7876 - 7882

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被引用次数: 26

摘要

The product ratios observed upon fluorodeiodination of a series of caged cyclobutane- containing iodides are explained on the basis of the relative energies of the intermediate cations involved. The relative energies of these cations have been evaluated by ab initio calculations with the inclusion of electron correlation (MP2/6-31G*//RHF/3-21G; MP2/6- 31G**), the results of which lend support to the view that hyperconjugative involvement of ...