Reactions of trimethylsilylpentafluorobenzene and triethylgermylpentafluorobenzene with nucleophilic reagents

…, LN Rogoza, IV Stennikova, GG Furin

文献索引：Bardin, V.V.; Rogoza, L.N.; Stennikova, I.V.; Furin, G.G. Journal of Fluorine Chemistry, 1992 , vol. 59, # 2 p. 165 - 177

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被引用次数: 9

摘要

Abstract This paper reports the results of studies on the reactions of trialkylsilyl-and germyl- pentafluorobenzenes with O-, N, S-and C-nucleophiles, and with LiAlH 4. Depending on the nature of the nucleophilic reagent, its attack is oriented towards a heteroatom (RO−, RS−), the C-4 atom of the pentafluorophenyl ring (BuLi, LiA1H 4, piperidyl-lithium) or at both electrophilic centres (piperidine, RS−).