Journal of the American Chemical Society

Hyperfine coupling patterns in the 2, 3-naphthobarrelene and 2, 3-naphthobarrelane radical anions

JR Dodd, GV Sanzero

文献索引：Dodd,J.R.; Sanzero,G.V. Journal of the American Chemical Society, 1975 , vol. 97, # 17 p. 4917 - 4922

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被引用次数: 3

摘要

Abstract: The radical anions of 2, 3-naphthobarrelene (2) and 2, 3-naphthobarrelane (3) were studied by ESR spectroscopy and polarography in order to investigate the importance of long-range coupling, 1, 3-na interaction, ion pairing phenomena, and steric and strain effects in these species. The magnitudes of the two largest hyperfine splitting constants (hfsc's) of 2.-and 3.-were found to vary appreciably as a function of the solvent and the ...