Organic letters

Efficient preparation of terminal conjugated dienes by coupling of dienol phosphates with Grignard reagents under iron catalysis

G Cahiez, V Habiak, O Gager

文献索引：Cahiez, Gerard; Habiak, Vanessa; Gager, Olivier Organic Letters, 2008 , vol. 10, # 12 p. 2389 - 2392

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被引用次数: 54

摘要

An efficient new route to prepare stereoselectively terminal conjugated dienes by coupling Grignard reagents and dienol phosphates in the presence of Fe (acac) 3 is described. The synthetic utility of this new iron-catalyzed procedure is illustrated by the synthesis of the pheromone of Diparopsis castanea according to a very expeditious strategy.